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　　要求考過(guò)有機(jī)化學(xué)，近期復(fù)試，有意者請(qǐng)直接用email聯(lián)系：zhaobg2006@shnu.edu.cn

　　個(gè)人主頁(yè)：http://shenghuan.shnu.edu.cn/Default.aspx?tabid=10586

　　主要研究方向：

　　[1]新型有機(jī)反應(yīng)的發(fā)展。

　　[2]不對(duì)稱催化。

　　[3]天然產(chǎn)物全合成。

　　發(fā)表論文：

　　[39]Feng Liu, Jiaxin Tian, Yong Liu, Chuangan Tao, Hao Zhu, Aina Zhang, Dongfang Xu and Baoguo Zhao* “Decarboxylative Umpolung of Conjugated Enal to β-Carbanion for Intramolecular Nucleophilic Addition to Aldehyde” Org. Chem. Fron. in review.

　　[38]Xiaoyu Lan, Chuangan Tao, Xuliang Liu, Aina Zhang, Baoguo Zhao* “Asymmetric Transamination of α-Keto Acids Catalyzed by Chiral Pyridoxamines” Org. Lett. 2016, 18, 3658.

　　[37]Yong Ethan Liu, Zhaole Lu, Bo Li, Jiaxin Tian, Feng Liu, Junyu Zhao, Chengkang Hou, Yingkun Li, Lili Niu, Baoguo Zhao* “Enzyme-Inspired Axially Chiral Pyridoxamines Armed with a Cooperative Lateral Amine Chain for Enantioselective Biomimetic Transamination” J. Am. Chem. Soc. 2016, 138, 10730.

　　[36]Jianfeng Chen, Junyu Zhao, Xing Gong, Dongfang Xu *, Baoguo Zhao * “A new type of chiral-pyridoxamines for catalytic asymmetric transamination of ?-keto acids” Tetrahedron Lett. 2016, 57, 4612.

　　[35]Limin Shi, Chuangan Tao, Qin Yang, Yong Ethan Liu, Jing Chen, Jianfeng Chen, Jiaxin Tian, Feng Liu, Bo Li, Yongling Du, Baoguo Zhao* “Chiral Pyridoxal-Catalyzed Asymmetric Biomimetic Transamination of α-Keto Acids” Org. Lett. 2015, 17, 5784.

　　[34]Bin Rong, Qin Yang, Hong Xu, Yifan Hu, Xuejing Cheng, Yong Liu, Baoguo Zhao* “Pd-catalyzed Asymmetric α-Allylic Alkylation of Thioamides” Tetrahedron Lett. 2015, 56, 595.

　　[33]Juan Xu, Jing Chen, Lei Ding, Xuliang Liu, Dongfang Xu, Baoguo Zhao* “Synthesis of α-Methylene-γ-amino acid Esters from Aldehydes via Aminative Umpolung Strategy” Adv. Synth. Catal. 2014, 356, 3219.

　　[32]Xuliang Liu, Ang Gao, Lei Ding, Juan Xu, Dongfang Xu, Baoguo Zhao* “Aminative Umpolung Synthesis of Vicinal Amines from Aromatic Aldehydes” Org. Lett. 2014, 16, 2118.

　　[31]Lei Ding, Jing Chen, Yifan Hu, Juan Xu, Xing Gong, Dongfang Xu, Baoguo Zhao*, Hexing Li “Aminative Umpolung of Aldehydes to α-Amimo Anion Equivalents for Pd-catalyzed Allyation: An Efficient Synthesis of Homoallylic Amines” Org. Lett. 2014, 16, 720.

　　[30]Bing Rong, Lei Ding, Hailei Yu, Qing Yang, Xuliang Liu, Dongfang Xu, Baoguo Zhao* “Pd-Catalyzed Allylic Alkylation of Thioamides” Tetrahedron Lett. 2013, 54, 6501.

　　[29]Baoguo Zhao, Zhaobin Han, Kuiling Ding* “N-H Functions in Organometallic Catalysis” Angew. Chem. Int. Ed. 2013, 52, 4744.

　　[28]Hailei Yu, Xuliang Liu, Lei Ding, Qin Yang, Bin Rong, Ang Gao, Baoguo Zhao*, Haifeng Yang “Pd-Catalyzed α-Arylation of Thioamides” Tetrahedron Lett. 2013, 54, 3060.

　　[27]Richard G. Cornwall, Baoguo Zhao, Yian Shi* “Catalytic Asymmetric Synthesis of Cyclic Sulfamides from Conjugated Dienes” Org. Lett. 2013, 15, 796.

　　[26]Yingguang Zhu, Baoguo Zhao, Yian Shi* “Highly Efficient Cu(I)-Catalyzed Oxidation of Alcohols to Ketones and Aldehydes with Diaziridinone” Org. Lett. 2013, 15, 992.

　　[25]Thomas A. Ramirez, Baoguo Zhao and Yian Shi* “Recent advances in transition metal-catalyzed sp3 C–H amination adjacent to double bonds and carbonyl groups” Chem. Soc. Rev. 2012, 41, 931-942.

　　[24]Baoguo Zhao, Xingao Peng, Yingguang Zhu, Thamos A. Ramirez, Richard G. Cornwall, Yian Shi* “Cu(I)-Catalyzed Diamination of Conjugated Dienes. Complementary Regioselectivity from Two Distinct Mechanistic Pathways” J. Am. Chem. Soc. 2011, 133, 20890-20900.

　　[23]Xingao Peng, Yingguang Zhu, Thomas A. Ramirez, Baoguo Zhao, Yian Shi* “New Reactivity of Oxaziridine: Pd(II)-Catalyzed Aromatic C-H Ethoxycarbonylation via C-C Bond Cleavage” Org. Lett. 2011, 13, 5244-5247.

　　[22]Richard G. Cornwall, Baoguo Zhao, Yian Shi* “Complementary Regioselectivity in the Cu(I)-Catalyzed Diamination of Conjugated Dienes To Form Cyclic Sulfamides” Org. Lett. 2011, 13, 434-437.

　　[21]Baoguo Zhao, Xingao Peng, Sunliang Cui, Yian Shi* “Cu(I)-catalyzed Regioselective Diamination of Conjugated Dienes via Dual Mechanistic Pathways” J. Am. Chem. Soc. 2010, 132, 11009-11011.

　　[20]Baoguo Zhao, Haifeng Du, Sunliang Cui, Yian Shi* “Synthetic and Mechanistic Studies of Pd(0)-Catalyzed Diamination of Conjugated Dienes” J. Am. Chem. Soc. 2010, 132, 3523-3532.

　　[19]Baoguo Zhao, Haifeng Du, Renzhong Fu, Yian Shi* “Pd(0)-Catalyzed Asymmetric Allylic and Homoallylic Diamination of 4-Phenyl-1-butene with Di-tert-butyldiaziridinone” Org. Synth. 2010, 87, 263.

　　[18]Thamos A. Ramirez, Baoguo Zhao, Yian Shi* “An effective C-C Double bond formation via Cu(I)-Catalyzed dehydrogenation” Tetrahedron Lett. 2010, 51, 1822-1825.

　　[17]Baoguo Zhao, Haifeng Du, Yian Shi* “Cu(I)-catalyzed Diamination of Conjugated Olefins with Tunable Counteranions. A Possible Approach to Asymmetric Diamination” J. Org. Chem. 2009, 74, 8392-8395.

　　[16]Baoguo Zhao, Haifeng Du, Yian Shi* “Cu(I)-Catalyzed C-H α-Amination of Aryl Ketones: Direct Synthesis of Imidazolinones” J. Org. Chem. 2009, 74, 4411-4413.

　　[15]Yuehong Wen, Baoguo Zhao, Yian Shi* “Cu(I)-Catalyzed Diamination of Disubstituted Terminal Olefins: An Approach to Potent NK1 Antagonist” Org. Lett. 2009, 11, 2365-2368.

　　[14]Rengzhong Fu, Baoguo Zhao, Yian Shi* “Synthesis of (+)-CP-99,994 via Pd(0)-Catalyzed Asymmetric Allylic and Homoallylic C-H Diamination of Terminal Olefin” J. Org. Chem. 2009, 74, 7577-7580.

　　[13]Haifeng Du, Baoguo Zhao, Yian Shi* "Pd(0)-Catalyzed Diamination of trans-1-Phenyl-1,3-butadiene with Di-tert-butyldiaziridinone as Nitrogen Source” Org. Synth. 2009, 86, 315.

　　[12]Baoguo Zhao, Haifeng Du, Yian Shi* “A Cu(I)-Catalyzed C-H α-Amination of Esters. Direct Synthesis of Hydantoins” J. Am. Chem. Soc. 2008, 130, 7220-7221.

　　[11]Baoguo Zhao, Haifeng Du, Yian Shi* “Cu(I)-Catalyzed Cycloguanidination of Olefins” Org. Lett, 2008, 10, 1087-1090.

　　[10]Haifeng Du, Baoguo Zhao, Yian Shi* “Catalytic Asymmetric Allylic and Homoallylic Diamination of Terminal Olefins via Formal C-H Activation” J. Am. Chem. Soc. 2008, 130, 8590-8591.

　　[9]Haifeng Du, Baoguo Zhao, Weicheng Yuan, Yian Shi* “Cu(I)-Catalyzed Asymmetric Diamination of Conjugated Dienes” Org. Lett. 2008, 10, 4231-4234.

　　[8]Baoguo Zhao, Xingao Peng, Zheng wang, Chungu Xia, Kuiling Ding* “Modular Chiral Bidentate Phosphonites: Design, Synthesis, and Application in Catalytic Asymmetric Hydroformylation Reactions” Chem. Eur. J. 2008, 14, 7847-7857.

　　[7]Baoguo Zhao, Weicheng Yuan, Haifeng Du, Yian Shi* “Cu(I)-Catalyzed Intermolecular Diamination of Activated Terminal Olefins” Org. Lett. 2007, 9, 4943-4945.

　　[6]Haifeng Du, Baoguo Zhao, Yian Shi* “A Facile Pd(0)-Catalyzed Regio- and Stereoselective Diamination of Conjugated Dienes and Trienes” J. Am. Chem. Soc. 2007, 129, 762-763.

　　[5]Haifeng Du, Weicheng Yuan, Baoguo Zhao, Yian Shi* “A Pd(0)-Catalyzed Diamination of Terminal Olefins at Allylic and Homoallylic Carbons via Formal C-H Activation under Solvent-Free Conditions” J. Am. Soc. Chem. 2007, 129, 7496-7497.

　　[4]Haifeng Du, Weicheng Yuan, Baoguo Zhao, Yian Shi* “Catalytic Asymmetric Diamination of Conjugated Dienes and Triene” J. Am. Soc. Chem. 2007, 129, 11688-11689.

　　[3]Weicheng Yuan, Haifeng Du, Baoguo Zhao, Yian Shi* “A Mild Cu(I)-Catalyzed Regioselective Diamination of Conjugated Dienes” Org. Lett. 2007, 9, 2589-2591.

　　[2]Baoguo Zhao, Zheng Wang, Kuiling Ding* “Practical by Ligand Design: A New Generation of Monodentate Phosphoramidite Ligands for Rhodium Catalyzed Enantioselective Hydrogenations” Adv. Synth. Catal. 2006, 348, 1049-1057

　　[1]Min Zhang, Huiying An, Baoguo Zhao, Jianhua Xu* “Aromatic annulation strategy for naphthalenes fused at 1,2- and 3,4-positions with two heterocycles” Org. Biomol. Chem. 2006, 4, 33-35.

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